Méthodes d'estimation, SIE 3e semestre, GC 5e semestre
Propriétés de composants organiques
Compensation conditionnelle pour un composant 

sigmarelS = 0.03

sigmalogK = 0.10

obs = [[ 1.26e-03]
 [ 1.78e-04]
 [ 1.45e-01]
 [ 2.00e-02]
 [ 6.96e+03]
 [ 1.02e+03]
 [-2.16e+00]
 [ 4.82e+00]
 [ 6.66e+00]] 

w = [[-6.1000e-07]
 [ 4.6320e-02]
 [ 1.0939e-01]
 [-9.8180e-02]
 [ 1.1243e-01]] 

B = [[ 2.0000e-02 -1.4500e-01 -1.7800e-04  1.2600e-03  0.0000e+00  0.0000e+00
   0.0000e+00  0.0000e+00  0.0000e+00]
 [ 1.0200e+03 -6.9600e+03  0.0000e+00  0.0000e+00 -1.7800e-04  1.2600e-03
   0.0000e+00  0.0000e+00  0.0000e+00]
 [ 0.0000e+00  2.4330e+03  0.0000e+00 -2.1661e+01  0.0000e+00  0.0000e+00
  -1.0000e+00  0.0000e+00  0.0000e+00]
 [ 0.0000e+00  2.4330e+03  0.0000e+00  0.0000e+00  0.0000e+00 -4.2371e-04
   0.0000e+00  0.0000e+00  1.0000e+00]
 [ 0.0000e+00  0.0000e+00  0.0000e+00  2.1661e+01  0.0000e+00 -4.2371e-04
   0.0000e+00  1.0000e+00  0.0000e+00]] 

sigmaS= [3.780e-05 5.340e-06 4.350e-03 6.000e-04 2.088e+02 3.060e+01] 

Kll = [[1.4288e-09 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 2.8516e-11 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 1.8922e-05 0.0000e+00 0.0000e+00 0.0000e+00
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 3.6000e-07 0.0000e+00 0.0000e+00
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 4.3597e+04 0.0000e+00
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 9.3636e+02
  0.0000e+00 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00
  1.0000e-02 0.0000e+00 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00
  0.0000e+00 1.0000e-02 0.0000e+00]
 [0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00 0.0000e+00
  0.0000e+00 0.0000e+00 1.0000e-02]] 

vcomp = [[ 3.6261e-06]
 [-2.4722e-07]
 [ 2.1254e-03]
 [-2.6987e-04]
 [-1.1533e+02]
 [ 1.6169e+01]
 [-1.0415e-01]
 [ 1.2513e-01]
 [-9.0728e-02]] 

lcomp = [[ 1.2564e-03]
 [ 1.7825e-04]
 [ 1.4287e-01]
 [ 2.0270e-02]
 [ 7.0753e+03]
 [ 1.0038e+03]
 [-2.0559e+00]
 [ 4.6949e+00]
 [ 6.7507e+00]] 

wcomp = [[-4.5313e-10]
 [ 3.0117e-05]
 [ 2.5854e-05]
 [ 8.9944e-05]
 [ 6.4090e-05]] 

sigmavcomp = [[2.2168e-05]
 [3.1124e-06]
 [2.5722e-03]
 [3.4659e-04]
 [1.1975e+02]
 [1.8189e+01]
 [9.9173e-02]
 [9.9179e-02]
 [9.9175e-02]] 

Rvcomp = [[ 1.0000e+00 -9.5018e-01 -4.7736e-01  4.5421e-01 -5.2246e-01  4.9797e-01
  -1.0694e-01  4.3131e-03  1.1125e-01]
 [-9.5018e-01  1.0000e+00  4.9815e-01 -5.2167e-01  4.5318e-01 -4.7819e-01
  -1.0892e-01  2.3301e-03  1.1125e-01]
 [-4.7736e-01  4.9815e-01  1.0000e+00 -9.5060e-01 -4.9983e-01  4.7694e-01
   1.1000e-01  1.0902e-01 -9.7468e-04]
 [ 4.5421e-01 -5.2167e-01 -9.5060e-01  1.0000e+00  4.7472e-01 -4.9969e-01
   1.1133e-01  1.1233e-01  1.0027e-03]
 [-5.2246e-01  4.5318e-01 -4.9983e-01  4.7472e-01  1.0000e+00 -9.5364e-01
  -1.3319e-03 -1.1004e-01 -1.0871e-01]
 [ 4.9797e-01 -4.7819e-01  4.7694e-01 -4.9969e-01 -9.5364e-01  1.0000e+00
   1.3129e-03 -1.0440e-01 -1.0572e-01]
 [-1.0694e-01 -1.0892e-01  1.1000e-01  1.1133e-01 -1.3319e-03  1.3129e-03
   1.0000e+00 -8.3251e-03  8.4189e-03]
 [ 4.3131e-03  2.3301e-03  1.0902e-01  1.1233e-01 -1.1004e-01 -1.0440e-01
  -8.3251e-03  1.0000e+00 -8.2905e-03]
 [ 1.1125e-01  1.1125e-01 -9.7468e-04  1.0027e-03 -1.0871e-01 -1.0572e-01
   8.4189e-03 -8.2905e-03  1.0000e+00]] 

sigmalcomp = [[3.0617e-05]
 [4.3392e-06]
 [3.5080e-03]
 [4.8977e-04]
 [1.7105e+02]
 [2.4607e+01]
 [1.2833e-02]
 [1.2784e-02]
 [1.2820e-02]] 

Rlcomp = [[ 1.      0.4935  0.2534 -0.2327  0.2648 -0.2665  0.5983 -0.0242 -0.6231]
 [ 0.4935  1.     -0.262   0.2648 -0.2276  0.2535  0.6038 -0.013  -0.6173]
 [ 0.2534 -0.262   1.      0.4933  0.2566 -0.2585 -0.6233 -0.6201  0.0055]
 [-0.2327  0.2648  0.4933  1.     -0.2352  0.2614 -0.6088 -0.6167 -0.0055]
 [ 0.2648 -0.2276  0.2566 -0.2352  1.      0.4935  0.0072  0.5977  0.5888]
 [-0.2665  0.2535 -0.2585  0.2614  0.4935  1.     -0.0075  0.5987  0.6045]
 [ 0.5983  0.6038 -0.6233 -0.6088  0.0072 -0.0075  1.      0.4991 -0.5033]
 [-0.0242 -0.013  -0.6201 -0.6167  0.5977  0.5987  0.4991  1.      0.4976]
 [-0.6231 -0.6173  0.0055 -0.0055  0.5888  0.6045 -0.5033  0.4976  1.    ]] 

QuotientGlobal = 0.95

z =  [[0.3439]
 [0.3397]
 [0.3497]
 [0.3337]
 [0.3289]
 [0.3533]
 [0.9835]
 [0.9837]
 [0.9836]] 

sumz =  5.0 

QuotientS = 0.71

QuotientlogK = 1.08
